Investigation on chiral capillary columns and their application in separation of enantiomers

作     者：ZHOU, Liang-Mo LOU, Xian-Wen LIU, You-Qin WANG, Qing-Hai ZHU, Dao-Qian Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116012 

作者机构：Dalian Institute of Chemical Physics Chinese Academy of Sciences Dalian 116012 

出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)

年 卷 期：1992年第10卷第5期

页      面：430-433页

核心收录：

学科分类：07[理学] 0703[理学-化学] 

基　　金：the National Natural Science Foundation of China 

主　　题：CSP Investigation on chiral capillary columns and their application in separation of enantiomers 

摘      要：Six chiral diamide stationary phases (CSPs), namely N-(3-carbobenzoxypropionyl)-L- Val-tert-butylamide (CSP-1), N-undecenoyl-L-Val-S-α-phenylethylamide (CSP-2), N-undecenoyl-L- Val-R-α-phenylethylamide (CSP-3), OV-225-L-Val-tert-butylamide (CSP-4), XE-60-L-Val-tert- butylamide (CSP-5) and polycyanoethyl vinyl siloxane-L-Val-tert-butylamide (CSP-6), were inves- tigated and CSP-6 was crosslinked within narrow bore (70 μm) fused silica capillary columns. The separation of amino acid enantiomers on this narrow bore column by gas chromatography (GC) is illustrated.