Dynamics of electrodeposition of tetraethylthioram disulphide(TETD) on pyrite surface

作     者：QIN Wen-qing,QIU Guan-zhou,HU Yue-hua,XU Jing (Department of Mineral Enginering, Central South University, Changsha 410083, Ch ina) 

作者机构：Department of Mineral Enginering Central South University Changsha China 

出 版 物：《Journal of Central South University》 (中南大学学报（英文版）)

年 卷 期：2001年第13卷第3期

页      面：164-168页

核心收录：

学科分类：081902[工学-矿物加工工程] 0819[工学-矿业工程] 08[工学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0802[工学-机械工程] 0801[工学-力学（可授工学、理学学位）] 0702[理学-物理学] 

基　　金：TheSpecialFundfortheNationalExcellentDoctoralThesis(2 0 0 0 47) 

主　　题：electrode process pyrite electrochemistry of flotation 

摘      要：The electrode process of pyrite in diethyldithiocarbamate (DDTC) solution pH 11.4 was investigated by using cyclic voltammetry, potentiost atic and chronopotentiometry. Tetraethylthioram disulphide(TETD) was electrodepo sited on pyrite electrode surface as the electrode potential is higher than 0.2 V. The relationship of the current density caused by diffusion and reaction time can be ascertained as i =1/(9.08×10 -5 +4.77×10 -3 t 0.5 ) , and the diffusion coefficient of DDTC on pyrite surface is about 3.72×10 - 6 cm 2/s. At pH 11.4, the thickness of TETD adsorbed on pyr ite surface is about 1.63 molecule layer. The electrochemical dynamics equation of the reduction of TETD on pyrite surface is given as η =0.116-0.064log[1- ( t/τ ) 0.5 ]. The kinetic parameters were determined as follows: the ex change current density ( i 0) is 3.08 μA/cm 2; the transmission coeffi cient( α ) is 0.462.