Cobalt（Ⅱ）-Catalyzed Bis-isocyanides Insertion Reactions with Boric Acidsand Sulfonyl Azides via Nitrene Radical Coupling
Cobalt(Ⅱ)-Catalyzed Bis-isocyanides Insertion Reactions with Boric Acids and Sulfonyl Azides via Nitrene Radical Coupling作者机构：Key Laboratory of Organic Synthesis of Jiangsu Province College of Chemistry Chemical Engineering and Materials Science & Collaborative Innovation Center of Suzhou Nano Science and Technology Soochow University Suzhou Jiangsu 215123 China
出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)
年 卷 期：2018年第36卷第11期
页 面：1011-1016页
核心收录：
学科分类：07[理学]
基 金：We gratefully acknowledge the National Natural Science Foundation of China (Nos. 21772137 21542015 and 21672157) PAPD the Project of Scientific and Technologic Infrastructure of Suzhou (No. SZS201708) and the Major Basic Research Project of the Natural Science Foundation of the Jiangsu Higher Education Institutions (No. 16KJA150002)
主 题：Co(II)‐catalysis isocyanide boric acids azides nitrene radical C1 building blocks
摘 要：A Co(II)‐catalyzed effective synthesis of amidinium imine derivatives from the reaction of isocyanides and boric acids using organic azides as nitrene source has been developed. This protocol provides a new, environment‐friendly and simple strategy to construct amidinium imine derivatives with a range of substrates without any oxidants and additives.
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