Pentazole anion cyclo-N_5^-: a rising star in nitrogen chemistry and energetic materials

作     者：Pengcheng Wang Qiuhan Lin Yuangang Xu Ming Lu 

作者机构：School of Chemical Engineering Nanjing University of Science and Technology 

出 版 物：《Science China Chemistry》 (中国科学（化学英文版）)

年 卷 期：2018年第61卷第11期

页      面：1355-1358页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：supported by the National Natural Science Foundation of China (21771108  11702141  U1530101) 

主　　题：碳化学 精力 阴离子 氮 材料 稳定性 债券 

摘      要：Nitrogen and carbon are common elements in nature. The development of nitrogen chemistry, however, is obviously left behind by that of carbon chemistry. Prof. Christ [1] attributed this reason to the stability difference between nitrogen-nitrogen bond and carbon-carbon bond. From N-N, N=N to N-N bond, the bond dissociation energy increases significantly and the stability becomes worse rapidly.