Impact of impregnation pressure on desulfurization performance of Zn-based sorbents supported on semi-coke

作     者：Xianrong Zheng Weiren Bao Qingmai Jin Ruiyuan He Liping Chang Kechang Xie 

作者机构：Key Laboratory of Coal Science and TechnologyMinistry of Education and Shanxi ProvinceTaiyuan University of TechnologyTaiyuan 030024ShanxiChina College of Electrical and Power EngineeringTaiyuan University of TechnologyTaiyuan 030024ShanxiChina 

出 版 物：《Journal of Natural Gas Chemistry》 (天然气化学杂志（英文版）)

年 卷 期：2012年第21卷第1期

页      面：56-60页

核心收录：

学科分类：081702[工学-化学工艺] 082903[工学-林产化学加工工程] 08[工学] 0817[工学-化学工程与技术] 0829[工学-林业工程] 082201[工学-制浆造纸工程] 0822[工学-轻工技术与工程] 

基　　金：supported by the financial support of National Basic Research Program of China (2012CB723105) National Natural Science Foundation of China (20976117) Shanxi Province Natural Science Foundation(2010011014-3) Shanxi Province Basic Conditions Platform for Science and Technology Project (2010091015) 

主　　题：desulfurization high-pressure impregnation method semi-coke support ZnO sorbent 

摘      要：High-pressure impregnation, a new preparation method for sorbents to remove H2S from hot coal gas, is introduced in this paper. Semi-coke （SC） and ZnO is selected as the support and active component of sorbent, respectively. The sorbent preparation process includes high-pressure impregnation, filtration, ovendry and calcination. The aim of this research is to primarily study the effects of the impregnation pressure on physical properties and desulfurization ability of the sorbent. The desulfurization experiment was carried out in a fixed-bed reactor at 500 ~C and a simulated coal gas used in this work was composed of CO （33 vol%）, H2 （39 vol%）, H2S （300 ppm in volume）, and N2 （balance）. Experimental results show that the pore structure of the SC support can be improved effectively and ZnO active component can be uniformly dispersed on the support, with the small particle size of 10-500 nm. Sorbents prepared using high-pressure impregnation have better desulfurization capacity and their active components have higher utilization rate. P20-ZnSC sorbent, obtained by high-pressure impregnation at 20 atm, has the best desulfurization ability with a sulfur capacity of 7.54 g S/100g sorbent and a breakthrough time of 44 h. Its desulfurization precision and efficiency of removing H2S from the middle temperature gases can reach 〈 1 ppm and 〉99.7%, respectively, before sorbent breakthrough.