Controllable hydrothermal synthesis of star-shaped Sr3Fe2（OH）12 assemblies and their thermal decomposition and magnetic properties
Controllable hydrothermal synthesis of star-shaped Sr3Fe2（OH）12 assemblies and their thermal decomposition and magnetic properties作者机构：Department of Chemical Engineering Qufu Normal University Qufu 273165 China
出 版 物：《Particuology》 (颗粒学报（英文版）)
年 卷 期：2016年第14卷第1期
页 面：210-215页
核心收录：
学科分类：08[工学] 0805[工学-材料科学与工程（可授工学、理学学位）]
基 金：国家自然科学基金 山东省自然科学基金 the State Key Laboratory of Chemical Engineering, China
主 题：Hydrogarnet Hydrothermal Star shaped Thermal decomposition Magnetic property
摘 要：Pure phase star-shaped hydrogarnet Sr3Fe2（OH）12 assemblies were synthesized by a mild hydrothermal method （210℃, 12 h）, and the effects of the preparation conditions on the phase composition of the product were investigated. It was found that the impurity phases could be decreased or eliminated by increasing the molar ratio of Sr2＋ to Fe3＋, and that high temperatures favored the formation of Sr3 Fe2（OH）12 and reduced the concentration of CO32- -containing byproducts. The thermal decomposition of the star-shaped Sr3Fe2（OH）12 assemblies was examined, and the results showed that the dehydration process at higher temperatures is accompanied by the formation of SrFeO3-δ. Above 655 ℃, a solid state reaction between the SrFeO3-δ and Sr（OH）2 or SrCO3 results in the formation of Sr4Fe3O10-δ.The mag- netic properties of the as-synthesized Sr3Fe2（OH）12 and of samples calcined at different temperatures were assessed. A sample calcined at 575 ℃ exhibited greatly enhanced ferromagnetic properties, with a remanent magnetization of 1.28 emu/g and a coercivity of 4522.1 Oe at room temperature.
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