Molecular structure of imidazolate bridged binuclear zinc complex and its single crystal ESR spectra doped with bridged Cu—Zn complex
Molecular structure of imidazolate bridged binuclear zinc complex and its single crystal ESR spectra doped with bridged Cu—Zn complex作者机构:State Key Laboratory of Coordination Chemistry Nanjing University Nanjing 210008 Analysis Center Chengdu Branch of Chinese Academy of Sciences Chengdu 610015
出 版 物:《Chinese Journal of Chemistry》 (中国化学(英文版))
年 卷 期:1993年第11卷第3期
页 面:201-209页
核心收录:
主 题:Molecular structure of imidazolate bridged binuclear zinc complex and its single crystal ESR spectra doped with bridged Cu Zn complex ESR
摘 要:The X-ray crystal structure of [(dtma)ZnImZn(dtma)]ClO_4·2.5H_2O (Hdtma=4-Diethyl- enetriamineacetic acid) was *** crystal is of orthorhombic,space group Pbcn with a- 14.104(5),b=14.897(5),c=25.384(9),and Z=*** least-square refinement of the structure leads to conventional R factor of *** magnetic properties of [(dtma)CulmZn(dtma)]CIO_4·2.5H_2O were *** the single crystal ESR spectra of Zn—Im—Zn dimer doped with Cu—Im—Zn complex,the anisotropic g and A tensors and electronic spin-density of the Cu—Zn complex are obtained and the bonding nature of Cu is discussed.