Molecular structure of imidazolate bridged binuclear zinc complex and its single crystal ESR spectra doped with bridged Cu—Zn complex

作     者：MAO,Zong-Wan CHEN,Dong HAN,Shi-Ying SUI,Yun-Xia TANG,Wen-Xia State Key Laboratory of Coordination Chemistry,Nanjing University,Nanjing 210008YU,Kai-Bei Analysis Center,Chengdu Branch of Chinese Aacdemy of Sciences,Chengdu 610015 

作者机构：State Key Laboratory of Coordination Chemistry Nanjing University Nanjing 210008 Analysis Center Chengdu Branch of Chinese Academy of Sciences Chengdu 610015 

出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)

年 卷 期：1993年第11卷第3期

页      面：201-209页

核心收录：

学科分类：07[理学] 0703[理学-化学] 

主　　题：Molecular structure of imidazolate bridged binuclear zinc complex and its single crystal ESR spectra doped with bridged Cu Zn complex ESR 

摘      要：The X-ray crystal structure of [(dtma)ZnImZn(dtma)]ClO_4·2.5H_2O (Hdtma=4-Diethyl- enetriamineacetic acid) was *** crystal is of orthorhombic,space group Pbcn with a- 14.104(5),b=14.897(5),c=25.384(9),and Z=*** least-square refinement of the structure leads to conventional R factor of *** magnetic properties of [(dtma)CulmZn(dtma)]CIO_4·2.5H_2O were *** the single crystal ESR spectra of Zn—Im—Zn dimer doped with Cu—Im—Zn complex,the anisotropic g and A tensors and electronic spin-density of the Cu—Zn complex are obtained and the bonding nature of Cu is discussed.