Separation and estimation of nanofiltration membrane transport parameters for cerium and neodymium
Separation and estimation of nanofiltration membrane transport parameters for cerium and neodymium作者机构:Department of Chemical Engineering S. V. National Institute of TechnologySurat-395007 Gujarat India
出 版 物:《Rare Metals》 (稀有金属(英文版))
年 卷 期:2012年第31卷第5期
页 面:500-506页
核心收录:
学科分类:07[理学] 0806[工学-冶金工程] 070205[理学-凝聚态物理] 08[工学] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程(可授工学、理学学位)] 0703[理学-化学] 0702[理学-物理学]
主 题:cerium neodymium nanofiltration Spiegler-Kedem model
摘 要:Lanthanides are widely used in various commercial applications, which results in public exposure to them, and it is a matter of concern. Many methods were used to remove lanthanides from wastewaters generated from their commercial use. In the present work, nanofiltration membrane process was used to remove the cerium and neodymium from their respective feed solutions. The feed and permeates were analyzed for solute concentration by inductively coupled plasma-atomic emission spectroscopy. Irreversible thermodynamics Spiegler-Kedem model, in combination with the film theory, was used to estimate the membrane transport parameters, viz., reflection coefficient of membrane and solute permeability, and mass transfer coefficient to study their dependence on feed solute concentration.