ZSM-5沸石结晶度对乙苯叔丁基化对位选择性的影响(英文)

作     者：PUSHPARAJ Hemalatha MANI Ganesh MUTHIAHPILLAI Palanichamy VELAYUTHAM Murugesan PARK Yong-Ki CHOI Won Choon JANG Hyun Tae PUSHPARAJ Hemalatha;MANI Ganesh;MUTHIAHPILLAI Palanichamy;VELAYUTHAM Murugesan;PARK Yong-Ki;CHOI Won Choon;JANG Hyun Tae

作者机构：Department of Chemical Engineering Hanseo University Seosan-si 356 706 South Korea Department of Chemistry Anna University Chennai 600 025 India Green Chemistry Research Division Korea Research Institute of Chemical Technology Jang-dong 100. Daejeon 305 600 South Korea 

出 版 物：《催化学报》 (Chinese Journal of Catalysis)

年 卷 期：2013年第34卷第2期

页      面：294-304页

核心收录：

学科分类：081705[工学-工业催化] 0817[工学-化学工程与技术] 08[工学] 0703[理学-化学] 

基　　金：supported by grants from Korea CCSR&D Centre funded by the Ministry of Education Science and Technology of the Korean Government 

主　　题：ZSM-5 Fluoride medium P-selectivity Ethylbenzene Tert-butylation Zeolite 

摘      要：Highly crystalline ZSM-5 zeolites are important for para-selective alkylation of alkyl aromatics, because they carry few external acid sites for isomerization of p-dialkyl products. Such zeolites (Si/Al = 25, 50, and 75) were synthesized in a fluoride medium between pH 4 and 6. Their crystallinities, crystal sizes, and surface areas were higher than those of a commercial ZSM-5 zeolite. Their para selectivities in alkylation were tested for vapor-phase tert-butylation of ethylbenzene between 200 and 400 °C. As expected, all the catalysts showed more than 90% para selectivity. At 300 °C, ethylbenzene conversion decreased in the order ZSM-5(25, commercial) ZSM-5(25) ZSM-5(50) ZSM-5(75). The catalysts had weak, medium, and strong acid sites, but all the acid sites of ZSM-5(75) were weaker than those of ZSM-5(25) and ZSM-5(50). The high activity of commercial ZSM-5 was caused by its strong acid sites being stronger than those of the synthesized zeolites. Although the activity of the commercial catalyst was higher than those of the present catalysts, the selectivity for 4-t-butylethylbenzene (4-t-BEB) was low. The optimum feed ratio (ethylbenzene:t-butyl alcohol) was 2:1 and the feed rate was 1.65 h?1 for high ethylbenzene conversion and 4-t-BEB selectivity. Time-on-stream studies showed slow catalyst deactivation. Highly crystalline ZSM-5 zeolites are therefore better than a commercial zeolite for para-selective alkylation of alkyl aromatics. They do not require much post-modification for high para selectivity. A fluoride medium is therefore better than an alkaline medium for obtaining highly crystalline para-selective ZSM-5 zeolites.