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Synthesis of a new aromatic diacid containing pyridine ring and related polybenzimidazole

Synthesis of a new aromatic diacid containing pyridine ring and related polybenzimidazole

作     者:Tao Ma Yan Feng Li Shu Jiang Zhang Feng Chun Yang Chen Liang Gong Jiu Jiang Zhao 

作者机构:College of Chemistry and Chemical EngineeringState Key Laboratory of Applied Organic Chemistry Institute of Biochemical Engineering & Environmental TechnologyLanzhou UniversityLanzhou 730000China 

出 版 物:《Chinese Chemical Letters》 (中国化学快报(英文版))

年 卷 期:2010年第21卷第8期

页      面:976-978页

核心收录:

学科分类:090403[农学-农药学(可授农学、理学学位)] 081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 09[农学] 080501[工学-材料物理与化学] 0904[农学-植物保护] 0805[工学-材料科学与工程(可授工学、理学学位)] 0703[理学-化学] 

基  金:the research support from the Natural Science Foundation of Gansu Province(No. 096RJZA047) the State Key Laboratory of Applied Organic Chemistry of People's Republic of China 

主  题:Polybenzimidazoles Pyridine-containing diacid monomer Synthesis Thermal stabilities 

摘      要:A new aromatic diacid monomer containing pyridine unit,4-phenyl-2,6-bis[4-(4-carboxyphenoxy) phenyl]pyridine 3,was successfully synthesized in three steps,starting from *** corresponding pyridine-containing polybenzimidazole was prepared via polycondensation of 3 with tetraaminodiphenyl ether(TADE) in poly(phosphoric acid)(PPA).The resulting polybenzimidazole exhibits excellent solubility,good thermal stabilities and high thermal resistance.

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