Synthesis of Terpyridine Derivatives Containing β-Cyclodextrin

作     者：Xian Hong YIN 

作者机构：Department of ChemistryGuangxi University for NationalitiesNanning 530006 

出 版 物：《Chinese Chemical Letters》 (中国化学快报(英文版))

年 卷 期：2003年第14卷第5期

页      面：445-447页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：This work was supported by the Natural Science Foundation of Guangxi Province(No.0135009) the Youth Foundation of Guangxi University for Nationalities 

主　　题：Cyclodextrin terpyridine synthesis. 

摘      要：A novel b-cyclodextrin-based terpyridine derivatives has been prepared by the coupling of 4-(4-bromomethyl phenyl)- 2, 2:6, 2-terpyridine with mono-6-hydroxy permethylated b- cyclodextrin. The cyclodextrin dimmer appending a 4-phenyl-2,2:6,2- terpyridine spacer on the primary faces was synthesized by reaction of 4-phenyl-2,2:6,2-terpyridine-6,6-dicarbonitrile with an excess of 6-deoxy-6-O-tosyl-b-cyclodextrin.