CO_2 reforming of glycerol over La-Ni/Al_2O_3 catalyst:A longevity evaluative study

作     者：Kah Weng Siew Hua Chyn Lee Maksudur R.Khan Jolius Gimbun Chin Kui Cheng 

作者机构：Faculty of Chemical & Natural Resources EngineeringUniversiti Malaysia Pahang Centre of Excellence for Advanced Research in Fluid FlowUniversiti Malaysia Pahang Rare Earth Research CentreUniversiti Malaysia Pahang 

出 版 物：《Journal of Energy Chemistry》 (能源化学（英文版）)

年 卷 期：2015年第24卷第3期

页      面：366-373页

核心收录：

学科分类：081702[工学-化学工艺] 081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 

基　　金：supported by the Ministry of Education,Malaysia through MTUN-Co E Research Grant(RDU121216) FRGS Research Grant(RDU140112) 

主　　题：CO2reforming glycerol lanthanum longevity syngas 

摘      要：This paper reports on the longevity of glycerol-dry（CO2） reforming over the lanthanum（La） promoted Ni/Al2O3 *** XRD results showed that the Ni particle was well-dispersed in the presence of La *** addition,via the NH3-TPD analysis,it was found that the La promoter has reduced the acidity of Ni catalyst which may have explained the mitigation of carbon *** was determined that the 3.0 wt% La-promoted Ni/Al2O3 catalyst possessed the largest BET specific surface area of 97 m2 ***,it yielded the best catalytic longevity performance with conversion attained more than 90%,even after 72 h of reaction ***,it can be confirmed that the presence of CO2 during the glycerol dry reforming was essential in reducing carbon deposition,most likely via gasification *** has ensured a stability of catalytic activity for a long reaction period（72 h）.