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Efficient One-pot Synthesis of Pyrrolo[2,1-a]isoquinoline and Pyrrolo[1,2-a]quinoline Derivatives

Efficient One-pot Synthesis of Pyrrolo[2,1-a]isoquinoline and Pyrrolo[1,2-a]quinoline Derivatives

作     者:LIU Zhen-ming WU Lei SUN Jing YAN Chao-guo 

作者机构:Analysis and Test Center & Chemical EngineeringYangzhou University Yangzhou 225002 P. R. China College of Chemistry & Chemical Engineering Yangzhou University Yangzhou 225002 P. R. China 

出 版 物:《Chemical Research in Chinese Universities》 (高等学校化学研究(英文版))

年 卷 期:2012年第28卷第6期

页      面:990-993页

核心收录:

学科分类:081702[工学-化学工艺] 081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基  金:Supported by the National Natural Science Foundation of China(No.21172189) 

主  题:Indolizine Pyrrolo[2 1-a]isoquinoline One-pot reaction Three-component reaction 

摘      要:A one-pot sequential reaction for efficient synthesis of pyrrolo[2,1-a]isoquinoline and pyrrolo[1,2-a]quinoline derivatives has been *** reaction included firstly the Cu-catalyzed three-component reaction of isoquinoline(quinoline),acetylenedicarboxylate and alkynylbenzene and then Cs 2 CO 3-promoted intramolecular cyclization reaction of initially formed 1-alkenyl-2-alkynyl-1,2-dihydroisoquinoline(1,2-dihydroquinoline).

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