双(3-对甲苯基-2-硫代咪唑-1-基)-(3-甲基-5-苯基吡唑-1-基)硼氢酸根的镉及钴配合物的合成与结构表征(英文)
Syntheses and Crystal Structures of Cadmium(II) and Cobalt(II) Complexes with Hydrobis(3-p-tolyl-2-thioimidazol-1-yl)-(3-phenyl-5-methyl-pyrazol-1-yl) Borate作者机构:上海交通大学化学化工学院上海200240 中国科学院上海有机化学研究所上海200032
出 版 物:《无机化学学报》 (Chinese Journal of Inorganic Chemistry)
年 卷 期:2006年第22卷第8期
页 面:1507-1510页
核心收录:
学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 070301[理学-无机化学]
摘 要:Two new complexes CdL2 (1) and CoL2 (2) were synthesized by reactions of L {L =hydrobis(3-p-tolyl-2-thioimidazol-1-yl)-(3-phenyl-5-methyl-pyrazol-1-yl)borate} with cadmium(II) and cobalt(II) acetate respectively, and structurally characterized. The title complexes feature distorted trigonal dipyramidal geometries with a S4H donor set defined by the sulphur and hydrogen atoms of two tripodal sulfur-rich ligands. CCDC: 235514, 1; 244021, 2.