Structure Investigation of a Novel Nitrogen-rich Energetic Complex Tetrammine-cis- bis ; 5-nitro-2 H-tetrazole-N2 ） Cobalt; hi） Perchlorate Dihydrate

作     者：Li Zhimin Yin Ming Zhang Jianguo Zhang Tonglai Shu Yuanjie Yang Li Wu Bidong LI Zhi-min;YIN Ming;ZHANG Jian-guo;ZHANG Tong-lai;SHU Yuan-Jie;YANG Li;WU Bi-dong

作者机构：Beijing Institute of Technology State Key Laboratory of Explosion Science and Technology Beijing 100081 Institute of Chemical Materials China Academy of Engineering Physics Mianyang 621900 

出 版 物：《含能材料》 (Chinese Journal of Energetic Materials)

年 卷 期：2011年第19卷第1期

页      面：119-120页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 070301[理学-无机化学] 

基　　金：国家自然科学基金 project of State Key Laboratory of Science and Technology 国家教育部新世纪优秀人才支持计划 

主　　题：高氯酸盐 爆炸物 含哨基 高温分解 

摘      要：Energetic coordination compound with 5-nitro-tetrazole (NT) as ligand has gained more and more attentions due to its extreme explosive properties and ecological friendly pyrolysis products[1-6]. The research results in 1994 proposed from Sandia National Laboratories proves tetrammine-cis-bis (5-nitro-2H-tetrazole-N~2) cobalt (III) perchlorate (BNCP) to be a more powerful explosive and undergoes deflagration-to-detonation (DDT) transition more rapidly than pentaammine (5-cyanotetrazolato-N~2) cobalt (III) perchlorate (CP), has been used as a promising lead-free primary explosive in semiconductor bridge detonator, DDT detonator and laser ignition in the area of national defense in USA[2-3]. Superfine particles of BNCP was prepared and its properties was investigated by Yu and his co-workers, in 2007[7]. The crystal structures of BNCP determined at 293 K and 213 K were reported by Sandia National Laboratories in 1997 for the first time, which is agreement with each other closely[1]. Then, Sheng et al[8] obtained the same structure of BNCP, and reported more details. But now, we obtained a novel crystalline structure of tetrammine-cis-bis (5-nitro-2 H-tetrazole-N~2) cobalt (III) perchlorate dihydrate just with two lattice H_2O molecules, which exhibits a various packing method versus the anhydrous BNCP