Investigation of Light-harvest Material:Synthesis and Characterization of Nanometer Porphyrin Trimer
Investigation of Light-harvest Material:Synthesis and Characterization of Nanometer Porphyrin Trimer作者机构:CollegeofChemistryJilinUniversityChangchun130023P.R.China SchoolofChemistry&PharmaceuticsEastChinaUniversityofScienceandTechnologyShanghai200237P.R.China
出 版 物:《Chemical Research in Chinese Universities》 (高等学校化学研究(英文版))
年 卷 期:2004年第20卷第3期
页 面:262-265页
核心收录:
学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学]
基 金:SupportedbytheNationalNaturalScienceFoundationofChina(No .2 0 0 710 14 )
主 题:Nanometer porphyrin trimer ω -Bromopropylporphyrin ether Bridge-linking reagent
摘 要:ω -Bromopropylporphyrin ether synthesized from the raction of 1,3-dibromopropane as the bridge-linked reagent and 5-(4-hydroxyphenyl)-10,15,20-triphenylporphyrin (H_2MHTPP) as the matrix reacts with 5,15-di(4- hydroxyphenyl)-10,20-diphenyl porphyrin( trans -H_2DHDPP) to give the title nanometer porphyrin trimer. The characterization was carried out by means of elemental analyses,UV-Vis,IR, 1H NMR and XRD.