A New Catalyst for Hydrogen Transfer Hydrogenation of Acetophenone

作     者：Pian Pian XU Rong Hui ZHENG Jing Xing GAO Pei Qing HUANG Hui Lin WAN （Department of Chemistry and Stste Key Laboratory of Physical Chemistry of Solid Surface Xiamen University, Xiamen 361005 ） 

作者机构：XIAMEN UNIVDEPT CHEMXIAMEN 361005PEOPLES R CHINA XIAMEN UNIVSTATE KEY LAB PHYS CHEM & SOLID SURFACEXIAMEN 361005PEOPLES R CHINA 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：1997年第8卷第3期

页      面：255-258页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

主　　题：A New Catalyst for Hydrogen Transfer Hydrogenation of Acetophenone Pro Chen Wang 

摘      要：A new C-2-symmetric diamine/diphosphine Ruthenium (II) complex, RuCl2P2N2H4, was used as an excellent catalyst to carry out the catalytic hydrogen transfer reduction of acetophenone. The conversion of acetophenone to 2-phenylethanol was up to 99% under the following reaction conditions: substrate:Ru:(CH3)(2)CHOK = 200:1:12; reaction temperature of 65 degrees C; reaction time of 2 h; normal pressure. A hydride transfer mechanism was also discussed.