An efficient fluorination of β-ketosulfones promoted by a room-temperature ionic liquid at ambient conditions under ultrasound irradiation using Selectfluor^(TM) F-TEDA-BF_4

作     者：Mohammad Reza Poor Heravi 

作者机构：Department of ChemistryPayame Noor University(Pnu)P.O.Box.97AbharZanjanIran 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2010年第21卷第12期

页      面：1399-1402页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：Dutch Cancer Foundation(UvA 95-994) National Health and Medical Research Council of Australia(922608) 

主　　题：Fluorination Ultrasound irradiation β-Ketosulfones Selectfluor^TM Ionic liquids(ILs) 

摘      要：The fluorination reaction involving a β-ketosulfones by Selectfluor^TM was efficiently promoted by the ionic liquid, [Hbim]BF4 （IL） as a reaction medium with methanol as co-solvent at room temperature under ultrasonic irradiation to afford the corresponding mono and difluoro-β-ketosulfones in excellent yields. The advantages of this method include among others the use of a recyclable, non-volatile ionic liquid, which promotes this protocol under room temperature without the requirement of any added catalyst under ultrasonic irradiation.