Syntheses, Characterization and Crystal Structures of Two-dimensional 4,4′-Bipyridyl Lead Halides, PbI_2(4,4′-bpy) and PbBr_2(4,4′-bpy)

作     者：YINHan-dong CUIJi-chun 

作者机构：DepartmentofChemistryLiaochengUniversityLiaocheng252059P.R.China 

出 版 物：《Chemical Research in Chinese Universities》 (高等学校化学研究（英文版）)

年 卷 期：2004年第20卷第5期

页      面：548-550页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：Supported by the Natural Science Foundation of Shandong Province(No.L2 0 0 3B0 1) and the State Key L aboratory ofCrystal MaterialsShandong University 

主　　题：Bipyridyllead halide Synthesis Crystal structure 

摘      要：Two-dimensional 4,4-bipyridyllead halides, PbI_2(4,4′-bpy)(1) and PbBr_2(4,4′-bpy)(2), were synthesized. The structures were determined by means of X-ray single crystal diffraction. The structure shows a distorted octahedral configuration with six-coordinated central lead atoms. In crystals 1 and 2, the molecules are packed in a two-dimensional network structure through bridging halide atoms and 4,4′-bipyridine ligands between the adjacent lead atoms.