吸附制冷用复合吸附剂的吸附性能

作     者：崔群 陈海军 朱跃钊 姚虎卿 CUI Qun;CHEN Haijun;ZHU Yuezhao;YAO Huqing

作者机构：南京工业大学化学化工学院江苏南京210009 南京工业大学机械与动力工程学院江苏南京210009 

出 版 物：《化工学报》 (CIESC Journal)

年 卷 期：2005年第56卷第10期

页      面：1860-1864页

核心收录：

学科分类：081702[工学-化学工艺] 08[工学] 0817[工学-化学工程与技术] 

基　　金：江苏省应用基础项目(BJ97067).~~ 

主　　题：吸附制冷 复合吸附剂 吸附等温线 特征吸附功 吸附速率 

摘      要：Adsorption performance of adsorbents for the adsorption cooling cycle was discussed. Adsorption isotherms and adsorption rate of water or ethanol on composite adsorbents prepared by the authors (named M4-0132, M1- 0001, M1-9906 and M2-0003 respectively), were tested. The results of fitting to the micro-pore filling theory equation and calculation of characteristic ads orption work based on these pairs were presented. The results showed that the a mount of water adsorbed by composite adsorbents was as high as 2 times that by s ilica gel and 2.5 times that by 13X molecular sieve, respectively, and characte ristic adsorption work calculated was 2.55～4.78 kJ·mol-1, only 12%～29 % of that on 13X molecular sieve. The values of adsorption rate of water on com posite adsorbents were higher than that on silica gel. Analysis for ethanol ads orption on composite adsorbent, M1-0001, showed occurrence of capillary condens ation, which resulted in a considerably higher ethanol uptake than on activated carbon at higher relative vapor pressure. The characteristic adsorption work of ethanol on composite sorbents was 2.55～4.78 kJ·mol-1, merely 10%～20% of that on activated carbon. Based on comprehensive estimate of adsorption pro perties, including adsorption loading, characteristic adsorption work and adsorp tion rate etc., M4-0132 and M1-0001 composite adsorbents were more prefer red for the adsorption cooling process, and the preferable type of isotherm for adsorption cooling cycle appeared to be the Ⅴ type of Brunauer classification.