Isomerization and rearrangement of boriranes: from chemical rarities to functional materials

作     者：Soren K.Mellerup Suning Wang Soren K.Mellerup;王苏宁

作者机构：Department of ChemistryQueefs UniversityKingstonONK7L 3N6Canada School of Chemistry and Chemical EngineeringBeijing Institute of TechnologyBeijing 100081China 

出 版 物：《Science China Materials》 (中国科学（材料科学（英文版）)

年 卷 期：2018年第61卷第10期

页      面：1249-1256页

核心收录：

学科分类：08[工学] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 

基　　金：financially supported by the Natural Science and Engineering Research Council of Canada (RGPIN:1193993-2013) the National Natural Science Foundation of China (21501017) 

主　　题：Smart materials photochemistry boriranes 

摘      要：Stimuli responsive materials have recently been the subject of tremendous research efforts owing to their numerous potential applications. Although there currently exist many different types of ＂smart＂ materials, those based on photoresponsive transformations are especially attractive. In this review, we focus on a relatively new class of photochromic molecules based on the photochemistry of chelate organoborates, which form intensely colored, base-stabilized *** efforts to exploit the reactivity of these systems are summarized, and future prospects in materials science discussed.