Structure Characterization of Fluorosilicone Oils

作     者：Yang Jiedan Yang He Xu Jing Li Hangquan 

作者机构：Beijing University of Chemical Technology Beijing 100029 SINOPEC Research Institute of Petroleum Processing Beijing 100083 

出 版 物：《China Petroleum Processing & Petrochemical Technology》 (中国炼油与石油化工（英文版）)

年 卷 期：2011年第13卷第4期

页      面：53-57页

核心收录：

学科分类：081702[工学-化学工艺] 08[工学] 0817[工学-化学工程与技术] 

主　　题：fluorosilicone oil molecular structure lubricity antioxidant 

摘      要：Fluorosilicone oil is polysiloxane with alkyl side chains containing fluorine, and because of its excellent thermal oxidation stability, cold flow property and cryogenic property, it can be widely used as a high temperature lubricant in the field of military aerospace industry. Two kinds of fluorosilicone oils, FSiO-a and FSiO-b, were synthesized by different pro- cessing means. FTICR MS was used to collect the information on composition and structure of the two polymers, respec- tively. The test results show that the two fluorosilicone oils have different contents of fluorine-containing chain segments (m/ n value), the maximum distribution of m/n value of FSiO-a oil ranges from 0.22 to 0.25, and that of FSiO-b oil ranges from 0.4 to 0.67. Difference in synthesis techniques makes this discrepancy and affects the quality and thermal stability of the fluoro- silicone oils.