Recent advances in asymmetric reactions catalyzed by chiral phosphoric acids

作     者：Xin Li Qiuling Song 

作者机构：Institute of Next Generation Matter Transformation College of Chemical Engineering at Huaqiao University 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2018年第29卷第8期

页      面：1181-1192页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：Financial support from the National Natural Science Foundation of China (No. 21772046) the Recruitment Program of Global Experts(1000 Talents Plan) the Natural Science Foundation of Fujian Province(No. 2016J01064) Program of Innovative Research Team of Huaqiao University (No. Z14X0047)are gratefully acknowledged 

主　　题：Chiral phosphoric acids Asymmetric reactions Organocatalysis Conjugate addition Cycloaddition Mannich reaction Friedel–Crafts reactions 

摘      要：This review summarizes the very recent advances in asymmetric reactions catalyzed by chiral phosphoric acids（CPAs）, a family of versatile catalysts that catalyze a broad range of reactions to afford diverse chiral molecules. In the past years, different kinds of chiral phosphoric acids have been designed and developed into a privileged class of catalysts in asymmetric synthesis. A number of remarkable achievements have been made by many groups around the world. Due to length limitation, this review only summarizes those works published from January 2016 to November 2017. Meanwhile, catalytic systems which combine metal catalysts and chiral phosphoric acids will not be discussed in this review.