Direct synthesis of imines by 9-azabicyclo-[3,3,1]nonan-N-oxyl/KOH-catalyzed aerobic oxidative coupling of alcohols and amines

作     者：Yan Wan Jia-Qi Ma Chao Hong Mei-Chao Li Li-Qun Jin Xin-Quan Hu Bao-Xiang Hu Wei-Min Mo Nan Sun Zhen-Lu Shen 

作者机构：College of Chemical Engineering Zhejiang University of Technology 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2018年第29卷第8期

页      面：1269-1272页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：supported by the National Natural Science Foundation of China(No. 21376224) the Natural Science Foundation of Zhejiang Province(No. LY17B060007) Hangzhou Qianjiang Distinguished Experts Project 

主　　题：Imines Benzyl alcohols Amines ABNO Air 

摘      要：A simple and efficient method for preparation of imines by the oxidative coupling of benzyl alcohols with aromatic amines or aliphatic amines was developed. The reaction was catalyzed by 9-azabicyclo[3.3.1]nonan-N-oxyl（ABNO）/KOH with air as the economic and green oxidant. Under the optimal reaction conditions, a variety of imines were obtained in 80%-96% isolated yields.