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Electrospun and in situ self-polymerization of polyacrylonitrile containing gadolinium nanofibers for thermal neutron protection

Electrospun and in situ self-polymerization of polyacrylonitrile containing gadolinium nanofibers for thermal neutron protection

作     者:Chun-Hong Wang Li-Min Hu Zhi-Feng Wang Ming Zhang 

作者机构:School of Chemistry and Chemical Engineering Yangzhou University Testing CenterYangzhou University 

出 版 物:《Rare Metals》 (稀有金属(英文版))

年 卷 期:2019年第38卷第3期

页      面:252-258页

核心收录:

学科分类:082704[工学-辐射防护及环境保护] 08[工学] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程(可授工学、理学学位)] 0827[工学-核科学与技术] 

基  金:financially supported by Postgraduate Research & Practice Innovation Program of Jiangsu Province (No. KYLX_1337) the Excellent Doctorial Dissertations Fund of Yangzhou University 

主  题:Gadolinium Polyacrylonitrile Electrospinning In situ self-polymerization Thermal neutron shielding 

摘      要:In this work, the polyacrylonitrile containing gadolinium nanofibers for thermal neutron protection were successfully fabricated by electrospunning and followed by in situ self-polymerization. Scanning electron microscopy(SEM) and energy-dispersive spectroscopy(EDS) results show that there are no beads on the smooth surface of the nanofibers and gadolinium elements are uniformly dispersed in the matrix. The thermal analysis and FTIR results prove that gadolinium methacrylate is induced in situ selfpolymerization during the heat treatment. The leaching rate of Gd^(3+) decreases from 79.97% to 10.74% tested by lowfield nuclear magnetic resonance(LF-NMR) method after the self-polymerization of gadolinium methacrylate in the matrix when the nanofibers were immersed in water for7 days. The thermal neutron shielding analysis calculated by MCNP program shows that above 99% thermal neutrons are absorbed when traveling through the 2-mm-thick polyacrylonitrile containing gadolinium nanofibers.

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