Synthesis and Crystal Structure of a New Cadmium(Ⅱ) Polymer with One-dimensional Chain Structure:[Cd(5-hip)(phen)]_n·nH_2O (5-hip=5-Hydroxyisophthalate,phen=1,10-Phenanthroline)
Synthesis and Crystal Structure of a New Cadmium(Ⅱ) Polymer with One-dimensional Chain Structure:[Cd(5-hip)(phen)]_n·nH_2O (5-hip=5-Hydroxyisophthalate,phen=1,10-Phenanthroline)作者机构：Jilin Normal University Siping Department of Chemistry Tonghua Normal College
出 版 物：《Chinese Journal of Structural Chemistry》 (结构化学（英文）)
年 卷 期：2008年第27卷第7期
页 面：781-784页
核心收录：
学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学]
主 题：coordination polymer hydrothermal synthesis crystal structure
摘 要：A new metal-organic coordination polymer [Cd（5-hip）（phen）]n·nH2O 1 has been hydro- ermally synthesized and characterized by elemental analysis, IR, TG and single-crystal X-ray diffraction. The crystal of the complex crystallizes in monoclinic, space group P2/n with a = 8.8071（17）, b =12.386（2）, c = 16.981（3） A, β = 100.182（2）°, V = 1823.2（6） A^3, Mr=. 490.73, Dc =1.788 g/cm^3,μ（MoKa） = 1.240 mm^-1, F（000） = 976, Z= 4, the final R = 0.0458 and wR = 0.1373 for 2864 observed reflections （I 〉 2σ（I））. The Cd atoms are coordinated by two N atoms from the phen ligands and four O atoms from 5-hydroxyisophthalate ligands in a highly distorted octahedral geometry.
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