Preparation and characterization of La-Co alloy nanowire arrays by electrodeposition in AAO template under nonaqueous system
Preparation and characterization of La-Co alloy nanowire arrays by electrodeposition in AAO template under nonaqueous system作者机构:College of Chemistry and Chemical EngineeringShenzhen University College of MaterialShenzhen Key Laboratory of Special Functional MaterialsShenzhen University
出 版 物:《中国有色金属学会会刊:英文版》 (Transactions of Nonferrous Metals Society of China)
年 卷 期:2008年第18卷第3期
页 面:642-647页
核心收录:
学科分类:080503[工学-材料加工工程] 08[工学] 0805[工学-材料科学与工程(可授工学、理学学位)]
基 金:Project(04011311) supported by the Natural Science Foundation of Guangdong Province, China Project(2006B14001001) supported by the Science and Technology Plan of Guangdong Province, China Project(50471108) supported by the National Natural Science Foundation of China
摘 要:La-Co alloy nanowires can be made in pulse reversal current(PRC) and direct current(DC) electrodepositions under nonaqueous system, with the porous anodic aluminum oxide(AAO) as template. This membrane is subject to the dual-oxidation (two-step) anodizing. Scanning electron microscope(SEM) examination shows that all of the nanowires have uniform diameter about 200 nm, and their diameters are determined by the pore diameter of applied AAO template. X-ray energy dispersion analysis indicates that the chemical composition of La and Co elements is very close to 1-2 in stoichiometry. X-ray diffraction pattern investigation demonstrates that La-Co nanowire is the face-centered cubic(FCC) LaCo13.