An efficient oxidation of benzylic and alicylic compounds with water-soluble copper catalysts in t-butyl hydroperoxide at room temperature
An efficient oxidation of benzylic and alicylic compounds with water-soluble copper catalysts in t-butyl hydroperoxide at room temperature作者机构:College of Engineering Department of Chemical EngineeringKing Saud University Department of Chemistry and Biochemistry University of Moncton
出 版 物:《Chinese Chemical Letters》 (中国化学快报(英文版))
年 卷 期:2011年第22卷第6期
页 面:691-693页
核心收录:
学科分类:081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术]
基 金:Authors acknowledge NSERC of Canada and Department of Chemical Engineering King Saud University Riyadh Kingdom of Saudi Arabia for their support
主 题:Oxidation Bibenzyl Allyl benzene Indan 2-Biquinoline-4 4-dicarboxylic acid dipotassium salt(BQC) Tetrabutyl ammonium bromide(TBAC)
摘 要:The water soluble catalytic system comprising of CuCl_2 and 2,2-biquinoline-4,4-dicarboxylic acid dipotassium salt(BQC) is highly efficient organic metallic catalysts for selective oxidation of benzyiic and alicyciic compounds to the corresponding ketones, ex:indan to indanone,ethyl benzene to acetophenone.