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An efficient oxidation of benzylic and alicylic compounds with water-soluble copper catalysts in t-butyl hydroperoxide at room temperature

An efficient oxidation of benzylic and alicylic compounds with water-soluble copper catalysts in t-butyl hydroperoxide at room temperature

作     者:Ateeq Rahman S.M.Al Zahrani Abdel Aziz Nait Ajjou 

作者机构:College of Engineering Department of Chemical EngineeringKing Saud University Department of Chemistry and Biochemistry University of Moncton 

出 版 物:《Chinese Chemical Letters》 (中国化学快报(英文版))

年 卷 期:2011年第22卷第6期

页      面:691-693页

核心收录:

学科分类:081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 

基  金:Authors acknowledge NSERC of Canada and Department of Chemical Engineering King Saud University Riyadh  Kingdom of Saudi Arabia for their support 

主  题:Oxidation Bibenzyl Allyl benzene Indan 2-Biquinoline-4 4-dicarboxylic acid dipotassium salt(BQC) Tetrabutyl ammonium bromide(TBAC) 

摘      要:The water soluble catalytic system comprising of CuCl_2 and 2,2-biquinoline-4,4-dicarboxylic acid dipotassium salt(BQC) is highly efficient organic metallic catalysts for selective oxidation of benzyiic and alicyciic compounds to the corresponding ketones, ex:indan to indanone,ethyl benzene to acetophenone.

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