Clay-Supported Molybdenum-Based Catalysts for Higher Alcohol Synthesis from Syngas
粘土担载的钼基催化剂的制备、结构及CO加氢合成醇性能作者机构：Department of Chemical Physics University of Science and Technology of China Hefei 230026China National Synchrotron Radiation Laboratory University of Science and Technology of China Hefei 230029 China
出 版 物：《Chinese Journal of Chemical Physics》 (化学物理学报（英文）)
年 卷 期：2015年第28卷第5期
页 面：-页
核心收录：
学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学]
基 金：the National Natural Science Foundation of China the National Basic Research Program of China
主 题：Higher alcohol synthesis Clay support K-Co-Mo catalyst Syngas
摘 要：A kind of clay-supported K-Co-Mo catalyst was prepared by a sol-gel method combined with incipient wetness impregnation. The catalyst structure was characterized by X-ray diffraction, N2 adsorption-desorption, H2 temperature-programmed reduction, and X-ray photoelectron spectroscopy techniques and its catalytic performance for higher alcohol synthesis from syngas was investigated. The active components has a high dispersion on the clay support surface. The increase of the Mo loading promoted reduction of Mo6+ but had no significant influence on the reduction of Mo4+ and Co2+ species. After reduction, a kind of lower state Moδ+ (1δ4) species was observed on the surface. Compared with the unsupported catalyst, the clay supported K-Co-Mo catalysts showed much higher catalytic performance for alcohol formation. The reason can be explained that the supported catalyst have a high active surface area and the mesoporous structure prolonged the residence time of intermediates for alcohol formation to some extent, which promoted the formation of higher alcohols. The high activity of the catalyst reduced at 773 K may be attributed to the high content of Moδ+ (1δ4) species on the surface, which was regarded as the active site for the adsorption of nondissociative CO and responsible for the alcohol formation.
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