Controlled one-pot synthesis of RuCu nanocages and Cu@Ru nanocrystals for the regioselective hydrogenation of quinoline
Controlled one-pot synthesis of RuCu nanocages and Cu@Ru nanocrystals for the regioselective hydrogenation of quinoline作者机构：Department of Chemistry and Collaborative Innovation Center for Nanomaterial Science and EngineeringTsinghua UniversityBeijing 100084China
出 版 物：《Nano Research》 (纳米研究（英文版）)
年 卷 期：2016年第9卷第9期
页 面：2632-2640页
核心收录：
基 金：We appreciate the financial support from the National Natural Science Foundation of China (Nos.21325101 21231005 and 21171105)
主 题：bimetallics one-pot synthesis nanocages core-shell nanocrystals hydrogenation of quinoline
摘 要：RuCu nanocages and core–shell Cu@Ru nanocrystals with ultrathin Ru shells were first synthesized by a one-pot modified galvanic replacement reaction. The construction of bimetallic nanocrystals with fully exposed precious atoms and a high surface area effectively realizes the concept of high atom-efficiency. Compared with the monometallic Ru/C catalyst, both the RuCu nanocages and Cu@Ru core–shell catalysts supported on commercial carbon show superior catalytic performance for the regioselective hydrogenation of quinoline toward 1,2,3,4-tetrahydroquinoline. RuCu nanocages exhibit the highest activity, achieving up to 99.6% conversion of quinoline and 100% selectivity toward 1,2,3,4-tetrahydroquinoline. [Figure not available: see fulltext.] © 2015, Tsinghua University Press and Springer-Verlag Berlin Heidelberg.
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