Design, synthesis and nonlinear optical properties of “dendronized hyperbranched polymers”

作     者：WU WenBo HUANG LiJin FU YingJie YE Cheng QIN JinGui LI Zhen 

作者机构：Department of ChemistryWuhan University Institute of ChemistryChinese Academy of Sciences 

出 版 物：《Chinese Science Bulletin》 (Chinese Science Bulletin)

年 卷 期：2013年第58卷第22期

页      面：2753-2761页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 

基　　金：supported by the National Natural Science Foundation of China(21034006) 

主　　题：树枝状聚合物 非线性光学性质 超支化聚合物 柱状 非线性光学效应 设计 合成 DHP 

摘      要：A new type of dendritic polymer, named dendronized hyperbranched polymer (DHP), was prepared successfully by the macro-monomer approach. Thanks to the perfect 3D isolation effects, DHPG1 exhibited good NLO property with d 33 value of 133 pm/V, higher than its analogues of dendronized polymer and dendrimer, and its stability of NLO effect was also enhanced.