Synthesis of N-acetamide C_(60) nitride and its performance of optical limiting

作     者：TANG Guangshi, ZHU Hesun & SONG Yinglin Research Center of Materials Science, Beijing Institute of Technology, Beijing 100081, China Department of Applied Physics, Harbin Institute of Technology. Harbin 150001. China Department of Applied Chemiscy Beiji 

作者机构：Research Center of Materials Science Beijing institute of Technology Beijing China Department of Applied Chemistry Beijing University of Chemicals Technology Beijing China Department of Applied Physics Harbin Institute of Technology Harbin China 

出 版 物：《Chinese Science Bulletin》 (中国科学通报)

年 卷 期：2000年第45卷第2期

页      面：150-153页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：北京理工大学校科研和教改项目 

主　　题：C60 derivatives N-nitride structure optical limiting properties reverse saturation absorption. 

摘      要：N-acetamide C60 nitride (N-acetamide-1,2-dihydro-1,2-aza-fullerene[60]) has been synthesized by the reaction of C60 and azidoacetamide and initially characterized. Its mechanism was that the objective product is formed through intermediate triazoline. The computational study shows that N-nitride structure is thermodynamically more stable by using the semi-empirical AM1 SCF-MO method. The properties of optical limiting were tested by using double frequency Nd: YAG pulse laser system and showed that the optical limiting mechanism is reverse saturation absorption. At wavelength of 532 nm, compared with optical limiting for ns pulse, this new material has good optical limiting character for ps pulse. At wavelength of 707 nm. the capacity of optical limiting of the derivative is prior to C60-