Metal-organic frameworks for highly efficient oxygen electrocatalysis

作     者：Xiaobo He Fengxiang Yin Hao Wang Biaohua Chen Guoru Li 何小波;银凤翔;王昊;陈标华;李国儒

作者机构：State Key Laboratory of Organic‐Inorganic Composites Beijing University of Chemical Technology Beijing 100029 China Advanced Catalysis and Green Manufacturing Collaborative Innovation Center Changzhou University Changzhou 213164 Jiangsu China College of Chemical Engineering Beijing University of Chemical Technology Beijing 100029 China Beijing Key Laboratory of Energy Environmental Catalysis Beijing 100029 China Changzhou Institute of Advanced Materials Beijing University of Chemical Technology Changzhou 213164 Jiangsu China 

出 版 物：《Chinese Journal of Catalysis》 (催化学报（英文）)

年 卷 期：2018年第39卷第2期

页      面：207-227页

核心收录：

学科分类：081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 

基　　金：基金来源: 国家自然科学基金(21706010) 江苏省基础研究计划(自然科学基金) (BK20161200) 中央高校基本科研业务费项目(buctrc201526, PYCC1706) 常州市科技项目(CJ20160007) 常州大学江苏省先进催化与绿色制造协同创新中心创新型人才支持项目(ACGM2016-06-02, ACGM2016-06-03) 

主　　题：Metal‐organic frameworks Porous materials Electrocatalysis Oxygen reduction reaction Oxygen evolution reaction Energy storage and conversion 

摘      要：Metal‐organic frameworks(MOFs)are a series of highly porous crystalline materials,which are built from inorganic metal nodes and organic linkers through coordination *** unique porous structural features(such as high porosity,high surface areas,and highly ordered nanoporous structures)and designable structures and compositions have facilitated their use in gas capture,separation,catalysis,and energy storage and ***,the design and synthesis of pure MOFs and their derivatives have opened new routes to develop highly efficient electrocatalysts toward oxygen reduction reactions(ORR)and oxygen evolution reactions(OER),which are the core electrode reactions in many energy storage and conversion techniques,such as metal‐air batteries and fuel *** review first discusses recent progress in the synthesis and the electrocatalytic applications of pure MOF‐based electrocatalysts toward ORR or OER,including pure MOFs,MOFs decorated with active species,and MOFs incorporated with conductive *** following section focuses on the advancements of the design and preparation of various MOF‐derived materials-such as inorganic nano‐(or micro‐)structures/porous carbon composites,pure porous carbons,pure inorganic nano‐(or micro‐)structured materials,and single‐atom electrocatalysts-and their applications in oxygen ***,we present a conclusion and an outlook for some general design strategies and future research directions of MOF‐based oxygen electrocatalysts.