Tunable white-light emission of lanthanide(Ⅲ) hybrid material based on hectorite

作     者：Jiahui Ma Tianren Wang Caixia Liu Huanrong Li 

作者机构：Hebei Provincial Key Lab of Green Chemical Technology and High Efficient Energy Saving School of Chemical Engineering and Technology Hebei University of Technology Tianjin 300130 China 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2018年第29卷第2期

页      面：321-324页

核心收录：

学科分类：081702[工学-化学工艺] 08[工学] 0817[工学-化学工程与技术] 

基　　金：the National Natural Science Foundation of China (Nos. 21171046, 21271060, and 21236001) the Tianjin Natural Science Foundation(No. 13JCYBJC18400) the Hebei Natural Science Foundation(No. B2016202147) Educational Committee of Hebei Province(Nos. 2011141,LJRC021)for financial support 

主　　题：Hectorite Lanthanide Covalent bond Luminescence White light 

摘      要：In this work, we present novel trivalent lanthanide ions（Ln^3＋）-based luminescent hybrid materials, in which the organic ligands are covalently grafted on the hectorite templates and the Ln^3＋ ions can be well immobilized by the ligands through coordination bond. The hybrid materials exhibit tunable emission colors by varying the molar ratio of Eu^3＋ to Tb^3＋, and the one with Eu^3＋：Tb^3＋=1：1 exhibits excellent coordinate of（0.327, 0.328） located in the ＂white region＂ of the CIE 1931 chromaticity diagram（under300 nm UV illumination）. These properties make the hybrid composites suitable for fabricating optoelectronic devices such as full-color displays and white LED.