The glyco-regioisomerism effect on dynamic interactions between glycopolymers with galactose pendants and benzoxaborole-containing polymer

作     者：Pengfei Sun Sichao Tian Mingchang Lin Guosong Chen 

作者机构：Key Laboratory for Organic Electronics and Information Displays & Institute of Advanced Materials Jiangsu National Synergetic Innovation Center for Advanced Materials Nanjing University of Posts & Telecommunications The State Key Laboratory of Molecular Engineering of Polymers and Department of Macromolecular Science Fudan University 

出 版 物：《Science China Chemistry》 (中国科学（化学英文版）)

年 卷 期：2018年第61卷第1期

页      面：71-75页

核心收录：

学科分类：07[理学] 08[工学] 0703[理学-化学] 

基　　金：supported by the National Natural Science Foundation of China (21604042, 21504016, 91527305) the Natural Science Foundation of Jiangsu Province of China (BK20150843) NUPTSF (NY215017, NY215080) 

主　　题：glyco-regioisomerism benzoxaborole glycopolymers hydrogel glucose 

摘      要：This work investigated the effect of glyco-regioisomerism of glycopolymers on their dynamic interaction with benzoxaborole-containing polymers. Two kinds of glycopolymers, P-1-Gal and P-6-Gal, i.e. galactoside pendant group linked to the identical main chain through its anomeric(C1) and C6-hydroxyl group position, respectively, were studied. We found that P-6-Gal showed stronger binding strength to the PNIPAM-co-PBOB polymer than P-1-Gal did, which controlled the macroscopic property of the resultant hydrogels at a molecular level.