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Determination and Removal of Endocrine Disruptors in Wastewater by Activated Carbon

Determination and Removal of Endocrine Disruptors in Wastewater by Activated Carbon

作     者:MarceloA. Nolasco Kamila O. Guimaraes Grace Cardoso 

作者机构:School of Arts Sciences and Humanities University of Sao Paulo-USP Sao Paulo 03828-000 Brazil Graduate Program in Architecture and Urbanism (PPGARQ) Meridional Faculty (IMED) Passo Fundo-RS 99070-220 Brazil 

出 版 物:《Journal of Civil Engineering and Architecture》 (土木工程与建筑(英文版))

年 卷 期:2017年第11卷第7期

页      面:653-662页

学科分类:083002[工学-环境工程] 0830[工学-环境科学与工程(可授工学、理学、农学学位)] 07[理学] 08[工学] 09[农学] 0903[农学-农业资源与环境] 0713[理学-生态学] 

主  题:Activated carbon endocrine disruptors adsorption solid-phase extraction chromatographic analysis micropollutants 

摘      要:This study aimed to evaluate the EDC (endocrine disruptors compounds) in the city of Sao Paulo's water sources, from samples collected at predetermined sampling points and to evaluate the adsorptive capacity of these compounds in different types of activated carbon. The effects of these EDC on humans are not well established due to the necessary large exposure time for the effect's manifestation. After tests using powdered and granular activated carbon, all samples were filtered under vacuum using cellulose acetate membrane (0.45 μm) to remove eventual impurities, and posteriorly carded out the solid-phase extraction SPE (solid-phase extraction) and chromatographic analysis. The results lead to the conclusion that both powdered activated carbon have removal effectiveness of these compounds by adsorption. Furthermore, great amount of endocrine disruptors were found at several sampling points in river and city's water reservoirs, which shows different levels of pollution of water sources, some of them responsible for the watersupply of the city of Silo Paulo, Brazil.

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