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Copper-Catalysed Decarboxylative Trifluoromethylation of β-Ketoacids

Copper-Catalysed Decarboxylative Trifluoromethylation of β-Ketoacids

作     者:Xiaolan Xu Huanhuan Chen Jianbo He Huajian Xu 

作者机构:School of Chemistry and Chemical Engineering Hefei University of Technology Hefei Anhui 230009 China School of Medical Science Anhui Medical University Hefei Anhui 230009 China 

出 版 物:《Chinese Journal of Chemistry》 (中国化学(英文版))

年 卷 期:2017年第35卷第11期

页      面:1665-1668页

核心收录:

学科分类:07[理学] 0703[理学-化学] 

基  金:We gratefully acknowledge financial support from the National Natural Science Foundation of China (21472033) and the Fundamental Research Funds for the Central Universities. We thank Wen-Man Zhang and Bei Huang in this group for reproducing the results of compounds 3c  3e  and 3m 

主  题:β-ketoacids decarboxylative trifluoromethylation α-trifluoromethyl ketones 

摘      要:An efficient method for Cu-catalyzed decarboxylative trifluoromethylation offl-ketoacids to achieve a-trifluoro- methyl ketones was developed. A wide variety of synthetically useful α-trifluoromethyl ketones were obtained in modest to good yields under mild reaction conditions. The present method also exhibits good functional-group compatibility.

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