A simple and convenient method for the synthesis of S-aryl phosphorothioates catalyzed by cesium hydroxide

作     者：Yue-Jun Ouyang Yuan-Yuan Li Ning-Bo Li Xin-Hua Xu 

作者机构：Department of Chemistry and Chemical EngineeringHuaihua University College of Chemistry and Chemical EngineeringHunan University 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2013年第24卷第12期

页      面：1103-1105页

核心收录：

学科分类：081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 

基　　金：supported by the National Nature Science Foundation of China (Nos. 21273068  21172061  J1210040) 

主　　题：Cesium hydroxide Diaryldisulfides O O-Dialkyl-S-arylphosphorothioates 

摘      要：In the presence of a catalytic amount of cesium hydroxide, the corresponding S-aryl phosphorothioates can he obtained by the reactions of dialkyl phosphites with diaryldisulfides in excellent yields at room temperature, using DMSO as a solvent. The reaction mechanism was discussed. The method provides a new and expedient path for the preparation of $-aryl phosphorothioates.