Preparation and photocatalytic properties of ilmenite NiTiO_3 powders for degradation of humic acid in water
Preparation and photocatalytic properties of ilmenite NiTiO_3 powders for degradation of humic acid in water作者机构:Institute of Clean Technique for Chemical Engineering Taiyuan University of Technology Taiyuan 030024 China
出 版 物:《International Journal of Minerals,Metallurgy and Materials》 (矿物冶金与材料学报(英文版))
年 卷 期:2012年第19卷第4期
页 面:372-376页
核心收录:
学科分类:080503[工学-材料加工工程] 0709[理学-地质学] 0819[工学-矿业工程] 081705[工学-工业催化] 08[工学] 0806[工学-冶金工程] 0817[工学-化学工程与技术] 0708[理学-地球物理学] 0805[工学-材料科学与工程(可授工学、理学学位)] 0703[理学-化学] 0802[工学-机械工程] 0801[工学-力学(可授工学、理学学位)] 0702[理学-物理学]
基 金:supported by the National Natural Science Foundation of China (No. 20876104,21176168) Science and Technology Foundation of Shanxi Province, China (No. 20090311082)
主 题:photocatalysis nickel titanate degradation humic acid water treatment
摘 要:The powders of ilmenite structure NiTiO3 were prepared by a modified Pechini process using tetrabutyl titanate and nickel acetate as raw materials, and using citric acid and ethanol as a chelating agent and a solvent respectively. The powder samples were characterized by thermogravimetric and differential thermal analysis (TG-DTA) and X-ray diffraction (XRD). The photocatalytic activity of NiTiO3 under the irradiation of ultraviolet rays (UV) light was evaluated by degrading hurnic acid (HA) in water as a probe reaction. The possible photodegra- dation mechanism was studied by the examination of active species .OH, .O2, and holes (h+) through adding scavengers. The TG-DTA and XRD results indicated that the good crystal structure of ilmenite phase NiTiO3 could be obtained when the Ni-Ti citrate complex was cal- cined at 600℃. The photocatalytic activity experiments indicated that NiTiO3 had favourable photocatalytic activity under the irradiation of UV light, and the photocatalytic degradation rate of HA reached 95.3% after a 2.5 h reaction with the photocatalyst calcined at 600℃ and a photocatalyst dosage of 0.4 g/L. The possible photocatalytic mechanism was deduced that holes (h+) and .OH radicals are the major reactive active species in the photocatalytic reaction, and dissolved oxygen plays a weak role in the degradation of HA.