Preparation and properties of two new soluble carbazole-containing functional polyacetylenes

作     者：Wei Ju Zhu Zhen Yu Wu Ji Ming Song Cun Li 

作者机构：School of Chemistry and Chemical Engineering Anhui University Hefei 230039 China 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2011年第22卷第9期

页      面：1017-1020页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 

基　　金：supported by the National Natural Science Fund of China(No.21071002/B0111) the Natural Science Fund of Anhui Province(No.11040606M33) 

主　　题：Polyacetylene CV Hole-injection Carbazole Thermal stability 

摘      要：Two new functional polyacetylenes bearing carbazole group as pendant, poly { 3-[（4-ethynylstyryl）-N-butyl] carbazole } （P1 ） and poly{3-14-（prop-2-ynyloxy）phenyl-N-butyl]carbazole}（P2）, were prepared using [Rb（nbd）Cl]2-Et3N as catalyst. The polymers were soluble in common organic solvents such as CHCl3 and THF. Their structures and properties were characterized and evaluated with FTIR, lit NMR, UV, TGA, GPC, and CV, respectively. The results show that the polymers possess high thermal stability and well hole-injection property.