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THE STACKING INERACTION OF TERNARY COMPLEXES OF Zn(ATP)^(2-)AND PYRIDINE-LIKELIGANDS

THE STACKING INTERACTION OF TERNARY COMPLEXES OF Zn (ATP)^(2-) AND PYRIDINE-LIKELIGANDS

作     者:Le, XY Wu, FH Song, FY Ji, LN 

作者机构:Zhongshan Univ Dept Chem Guangzhou 610275 Peoples R China Nanjing Univ State Key Lab Coordinat Chem Nanjing 210008 Peoples R China 

出 版 物:《Chinese Chemical Letters》 (中国化学快报(英文版))

年 卷 期:1995年第6卷第9期

页      面:801-804页

核心收录:

学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

主  题:ATP COMPLEXES Zn AND 

摘      要:Abstract: The stability constants of ternary complexes of the type Zn (ATP) L2-.,where L=pyridine, 4-7 icoline, 3, 4- lutidine and 3, 5- lutidine,have been determined by potentiometric pll titration in aqueous solution and compared with the stabililty of the corresponding binary complexes ZuL2+. It has been observed that there is a stacking interact ion between the pyridine ring of the pyridine-like the ligands and the purine moiety of ATP in the ternary Zn (ATP) La- complexes and this stacking interaceion is stronger than that in corresponding Cu (ATP) L2- complexes.

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