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Resonance Rayleigh scattering spectrum for the chelate of lanthanum(Ⅲ) with sodium tanshinon ⅡA silate and its analytical application

Resonance Rayleigh scattering spectrum for the chelate of lanthanum(Ⅲ) with sodium tanshinon ⅡA silate and its analytical application

作     者:PENG Jingdong LIU Shaopu LIU Zhongfang SHI Yan 

作者机构:College of Chemistry and Chemical Engineering Southwest China Normal University Chongqing 400715 China College of Chemistry and Chemical Engineering Southwest China Normal University Chongqing 400715 China College of Chemistry and Chemical Engineering Southwest China Normal University Chongqing 400715 China College of Chemistry and Chemical Engineering Southwest China Normal University Chongqing 400715 China 

出 版 物:《Science China Chemistry》 (中国科学(化学英文版))

年 卷 期:2006年第49卷第5期

页      面:423-429页

核心收录:

学科分类:07[理学] 08[工学] 

基  金:This work was supported by the National Natural Science Foundation of China (Grant Nos. 20175018 and 20475045) 

主  题:lanthanum(Ⅲ), sodium tanshinon ⅡA silate, chelate, resonance Rayleigh scattering, analytical application. 

摘      要:In a pH 3.6―5.0 HAc-NaAc buffer solution, when sodium tanshinon ⅡA silate (STSⅡA) reacts with La(Ⅲ) to form a chelate, the resonance Rayleigh scattering (RRS) intensity can be en-hanced greatly and a new RRS spectrum will appear. The maximum RRS peak is located at 306 nm and the RRS intensity is proportional to the concentration of STSⅡA in a certain range. The method is very sensitive and the detection limit for STSⅡA (3σ/K) is 82.12 ng·mL?1. The optimum reaction condi-tions and the effect of coexisting substances have been investigated. A new, simple and fast method for the determination of STSⅡA based on RRS method is developed. It can be applied to the deter-mination of STSⅡA in the synthesis samples and Nuoxinkang injection. Combined with infrared ab-sorption and NMR spectra, the structure of the chelate and the reasons of RRS enhancement are also discussed.

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