Hydrothermal Synthesis and Characterization of a Novel Supramolecular Network Compound [Co(IN)_2(H_2O)_4](IN=Isonicotinate)

作     者：JIA Hong-bin YU Jie-hui DING Hong XU Ji-qing YE Ling JING Wei-jieWANG Tie-gang XU Jia-ning QU Xue-jian LI Zeng-chun 

作者机构：College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative ChemistryJilin UniversityChangchun 130023P.R.China Key Laboratory of Supramolecular Structure and Materials of Ministry of EducationJilin UniversityChangchun 130023P.R.China Department of ChemistryInner Mongolia University for NationalitiesTongliao 028000P.R.China 

出 版 物：《Chemical Research in Chinese Universities》 (高等学校化学研究(英文版))

年 卷 期：2002年第18卷第4期

页      面：385-388页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：Supported by the National Natural Science Foundation of China( No.2 973 3 0 90 ),the Research Funds for the DoctoralProgram of Higher Education,the State Key L aboratory of Coordination Chemistry Nanjing U niversity and the Funds ofInner Mongolia Edu 

主　　题：Hydrothermal synthesis Cobalt(Ⅱ) complex X-Ray diffraction Isonicotinate Supramolecule 

摘      要：A novel supramolecular compound, [Co(IN)_2(H_2O)_4](1), was synthesized by means of the hydrothermal method and its structure was characterized with elemental analysis, FT-IR spectrum, TGA and X-ray diffraction. Though the unit cell structure of the title compound is only monomeric, all these units as building blocks are assembled into a novel three-dimensional supramolecular network via the widely hydrogen-bonding and π-π stacking interactions.