Enhancement of Fenton oxidation for removing organic matter from hypersaline solution by accelerating ferric system with hydroxylamine hydrochloride and benzoquinone

作     者：Siwei Peng Weijun Zhang Jie He Xiaofang Yang Dongsheng Wang Guisheng Zeng 

作者机构：Key Laboratory of Jiangxi Province for Ecological Diagnosis-Remediation and Pollution ControlNanchang Hangkong University State Key Laboratory of Environmental Aquatic ChemistryResearch Center for Eco-Environmental SciencesChinese Academy of Sciences 

出 版 物：《Journal of Environmental Sciences》 (环境科学学报（英文版）)

年 卷 期：2016年第28卷第3期

页      面：16-23页

核心收录：

学科分类：083002[工学-环境工程] 0830[工学-环境科学与工程（可授工学、理学、农学学位）] 08[工学] 

基　　金：supported by the National Natural Science Foundation of China(Nos.51025830 41201498 and 51178360) 

主　　题：Saline solution Fenton oxidation Hydroxyl radicals Benzoquinone Hydroxylamine hydrochloride 

摘      要：Fenton oxidation is generally inhibited in the presence of a high concentration of chloride *** study investigated the feasibility of using benzoquinone（BQ） and hydroxylamine hydrochloride（HA） as Fenton enhancers for the removal of glycerin from saline water under ambient temperature by accelerating the ferric *** was found that organics removal was not obviously affected by chloride ions of low concentration（less than 0.1 mol/L）,while the mineralization rate was strongly inhibited in the presence of a large amount of chloride *** addition,ferric hydrolysis-precipitation was significantly alleviated in the presence of HA and BQ,and HA was more effective in reducing ferric ions into ferrous ions than HA,while the H_2O_2 decomposition rate was higher in the BQ-Fenton *** spin resonance analysis revealed that OH production was reduced in high salinity conditions,while it was enhanced after the addition of HA and BQ（especially HA）.This study provided a possible solution to control and alleviate the inhibitory effect of chloride ions on the Fenton process for organics removal.