Copper-Catalyzed Three-Component Azidotrifluoromethylation/Difunctionalization of Alkenes

作     者：Mingbo Yang Wenlu Wang Yin Liu Lijie Feng Xuexia Ju 

作者机构：Gansu Research Institute of Chemical IndustryLanzhouGansu 730020China Gansu Province Environmental Monitoring CenterLanzhouGansu 730020China 

出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)

年 卷 期：2014年第32卷第9期

页      面：833-837页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：We thank the Gansu Province Key Laboratory of Fine Chemical(No.1206RTSA022) the Gansu Province Science and Technology Innovation Service Platform Construction Plan(No.1306TTPA024)for financial support.We also acknowledge support from the Gansu Province Containing Fluorine Meticulous Chemicals R&D Platform Project and Program for Pharmaceutical Intermediates Innovation Research Team in Gansu Province(No.1207TTCA009) 

主　　题：azidotrifluoromethylation alkenes azide-containing 

摘      要：A novel three-component strategy for the azidotrifluoromethylation of alkenes has been presented *** reaction proceeded smoothly under gentle temperature and gave the bifunctional olefins in high ***,1,3-dipolar reactions between azide-containing products and phenylacetylene revealed great potential in molecular modification by using this method.