Copper-Catalyzed Cyanations of Aromatic Bromides with Benzoyl Cyanide
Copper-Catalyzed Cyanations of Aromatic Bromides with Benzoyl Cyanide作者机构:School of Petrochemical EngineeringChangzhou UniversityChangzhouJiangsu 213164China
出 版 物:《Chinese Journal of Chemistry》 (中国化学(英文版))
年 卷 期:2014年第32卷第12期
页 面:1221-1224页
核心收录:
学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学]
基 金:This project was financially supported by the National Natural Science Foundation of China(No.21302014) the Natural Science Foundation for Colleges and Universities of Jiangsu Province(13KJB150002) the Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology(grant No.BM2012110)
主 题:nitriles aromatic bromides benzoyl cyanide copper-catalysis cyanation
摘 要:Aromatic nitriles were synthesized through copper-catalyzed cyanations of aromatic bromides using benzoyl cyanide as the cyanide source.A series of functional groups were tolerated under the reaction conditions to provide the products in good ***,this protocol avoids using of highly toxic alkali cyanides and expensive palladium catalysts.