Synthesis of Quaternary α-Hydroxy Phosphonates via Direct Hydroxylation of Phosphonate Compounds

作     者：Jiyan Liu Wei Wang Rui Wang Lijun Gu 

作者机构：Key Laboratory of Chemistry in Ethnic Medicinal ResourcesState Ethnic Affairs Commission&Ministry of EducationYunnan Minzu UniversityKunmingYunnan 650500China 

出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)

年 卷 期：2015年第33卷第5期

页      面：559-562页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：the financial support from Program for Innovative Research Team(in Science and Technology)in University of Yunnan Province(IRTSTYN 2014-11) the State Ethnic Affairs Commission(12YNZ05) 

主　　题：quaternaryα-hydroxy phosphonates molecular oxygen direct hydroxylation 

摘      要：It was found for the first time that Cs_(2)CO_(3) serves as highly efficient catalyst for the direct hydroxylation reactions of phosphonates under mild *** reaction provides an efficient approach to quaternaryα-hydroxy phosphonates,which possess intriguing biological activities and are widely used in many areas.