Efficient C-S Cross-Coupling of Thiols with Aryl Iodides Catalyzed by Cu(OAc)_(2)·H_(2)O and 2,2'-Biimidazole
有芳基碘化物的 Thiols 的有效 CS 跨 Coupling 由 Cu (OAc ) 催化 2 · H 2O 和 2,2-Biimidazole作者机构:Key Laboratory of Organic Synthesis of Jiangsu ProvinceCollege of ChemistryChemical Engineering and Materials ScienceSoochow UniversitySuzhouJiangsu 215123China
出 版 物:《Chinese Journal of Chemistry》 (中国化学(英文版))
年 卷 期:2014年第32卷第3期
页 面:212-218页
核心收录:
学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学]
基 金:This work was supported by the Team Innovation Project of Soochow University
主 题:C-S cross coupling reaction Cu(OAc)_(2)·H_(2)O,2,2'-biimidazole aryl sulfides
摘 要:The classical Ullmann C-S cross coupling reaction of aryl iodides with aromatic/alkyl thiols under catalysis of 15 mol%Cu(OAc)_(2)·H_(2)O and 15 mol%2,2 -biimidazole works at 80℃in DMSO for 3 h to provide a variety of aryl sulfides in good to excellent yields.