On Desilylation of 13-Vertex Carborane 1,2-Me_(2)Si(CH_(2))_(2)-1,2-C_(2)B_(11)H_(11)

作     者：Jian Zhang Zuowei Xie 

作者机构：Department of ChemistryThe Chinese University of Hong KongShatinNew TerritoriesHong KongChina 

出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)

年 卷 期：2014年第32卷第8期

页      面：777-782页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：The work described in this paper was supported by grants from the Research Grants Council of the Hong Kong Special Administration Region(Nos.404610 and CUHK7/CRF/12G) 

主　　题：cage compounds carboranes cluster compounds desilylation ruthenacarboranes 

摘      要：The reasons for facile double desilylation of 13-vertex carborane 1,2-Me_(2)Si(CH_(2))_(2)-1,2-C_(2)B_(11)H_(11)(2)are discussed in this *** 13-and 14-vertex ruthenacarboranes bearing the same-CH_(2)SiMe_(2)CH_(2)-linkage have been prepared and structurally characterized for *** analyses of 13-and 14-vertex heteroboranes as well as control experiments suggest that the facile double desilylation of 2 on silica gel can be attributed to the joint actions of several factors involving the high ring-strain of exo five-membered C_(4)Si ring,Lewis acidity of Si atom and Brønsted acidity of silica surface.