Deriving phosphorus atomic chains from few-layer black phosphorus
Deriving phosphorus atomic chains from few-layer black phosphorus作者机构：State Key Laboratory of Silicon Materials School of Materials Science and Engineering Zhejiang University Hangzhou 310027 China Department of Physics and Beijing Key Laboratory of Optoelectronic Functional Materials & Micro-nano Devices Renmin University ot China Beijing 100872 China Key Laboratory of Strongly-coupled Quantum Matter Physics Hefei National Laboratory for Physical Sciences at Microscale and Department of Physics University of Science and Technology of China Hefei 230026 China Collaborative Innovation Center of Advanced Microstructures Nanjing University Nanjing 210093 China
出 版 物：《Nano Research》 (纳米研究（英文版）)
年 卷 期：2017年第10卷第7期
页 面：2519-2526页
核心收录：
学科分类：081704[工学-应用化学] 0809[工学-电子科学与技术（可授工学、理学学位）] 07[理学] 070205[理学-凝聚态物理] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 070301[理学-无机化学] 0702[理学-物理学]
基 金：This work was financially supported by the National Natural Science Foundation of China (Nos. 51472215 51222202 91433103 11274380 11622437 61674171 11227403 and 11534010) the National Basic Research Program of China (Nos. 2014CB932500 and 2015CB21004) the 111 project (No. B16042) and the Fundamental Research Funds for the Central Universities (No. 16XNLQ01). J. S. Q. was supported by the Outstanding Innovative Talents Cultivation Funded Programs 2016 of Renmin University of China. This work made use of the resources of the Center of Electron Microscopy of Zhejiang University. Calculations were performed at the Physics Laboratory for High-Performance Computing of Renmin University of China and at the Shanghai Supercomputer Center. We thank Prof. Ray F. Egerton for fruitful discussions and Dr. Qiang Xu for his assistance on in situ heating
主 题：black phosphorus one-dimensionalatomic chain density functional theory
摘 要：Phosphorus atomic chains, the narrowest nanostructures of black phosphorus （BP）, are highly relevant to the in-depth development of BP-based one-dimensional （1D） nano-electronics components. In this study, we report a top-down route for the preparation of phosphorus atomic chains via electron beam sculpturing inside a transmission electron microscope （TEM）. The growth and dynamics （i.e., rupture and edge migration） of 1D phosphorus chains are experimentally captured for the first time. Furthermore, the dynamic behavior and associated energetics of the as-formed phosphorus chains are further investigated by density functional theory （DFT） calculations. It is hoped that these 1D BP structures will serve as a novel platform and inspire further exploration of the versatile properties of BP.
维普期刊数据库